View source for Physics:Fibre-reinforced plastic

{{Short description|Composite material made of a polymer matrix reinforced with fibres}}
'''Fibre-reinforced plastic''' ('''FRP'''; also called '''fibre-reinforced polymer''', or in American English ''fiber'') is a [[Chemistry:Composite material|composite material]] made of a [[Chemistry:Polymer|polymer]] matrix reinforced with fibres. The fibres are usually glass (in fibreglass), [[Chemistry:Carbon fibers|carbon]] (in carbon-fibre-reinforced polymer), [[Chemistry:Aramid|aramid]], or basalt. Rarely, other fibres such as paper, wood, boron, or [[Chemistry:Asbestos|asbestos]] have been used. The polymer is usually an [[Chemistry:Epoxy|epoxy]], [[Chemistry:Vinyl ester resin|vinyl ester]], or [[Chemistry:Polyester|polyester]] thermosetting plastic, though [[Chemistry:Phenol formaldehyde resin|phenol formaldehyde resin]]s are still in use.

FRPs are commonly used in the aerospace, automotive, marine, and construction industries. They are commonly found in ballistic armour and cylinders for [[Chemistry:Self-contained breathing apparatus|self-contained breathing apparatus]]es.

==History==
[[Chemistry:Bakelite|Bakelite]] was the first fibre-reinforced plastic. Leo Baekeland had originally set out to find a replacement for [[Chemistry:Shellac|shellac]] (made from the excretion of lac bugs). Chemists had begun to recognize that many natural resins and fibres were polymers, and Baekeland investigated the reactions of phenol and formaldehyde. He first produced a soluble phenol-formaldehyde shellac called "Novolak" that never became a market success, then turned to developing a binder for [[Chemistry:Asbestos|asbestos]] which, at that time, was moulded with rubber. By controlling the pressure and temperature applied to [[Chemistry:Phenol|phenol]] and [[Physics:Formaldehyde|formaldehyde]], he found in 1905 he could produce his dreamed of hard mouldable material (the world's first synthetic plastic): bakelite.<ref name="time">{{cite magazine | last = Amato | first = Ivan | magazine = {{wipe|Time (magazine)}} | title=The Time 100: Leo Baekeland | date = 29 March 1999 | url = http://www.time.com/time/time100/scientist/profile/baekeland.html | url-status = dead |archive-url = https://web.archive.org/web/20070104122608/http://www.time.com/time/time100/scientist/profile/baekeland.html |archive-date = 4 January 2007}}</ref><ref name="History">{{cite web | last =  Trueman | first = C N| title = Plastic | work = The History Learning Site | date = 17 March 2015 | url = http://www.historylearningsite.co.uk/plastic.htm }}</ref> He announced his invention at a meeting of the [[Organization:American Chemical Society|American Chemical Society]] on 5 February 1909.<ref>{{cite news | title=New Chemical Substance | work={{wipe|The New York Times}} | date=6 February 1909 | url=https://timesmachine.nytimes.com/timesmachine/1909/02/06/101025892.pdf }}</ref>

The development of fibre-reinforced plastic for commercial use was being extensively researched in the 1930s. In the {{wipe|United Kingdom}}, considerable research was undertaken by pioneers such as Norman de Bruyne. It was particularly of interest to the aviation industry.<ref>Synthetic Resin – Use in Aircraft Construction, ''The Times'', London England, 5 October 1936, page 14, Issue 47497</ref>

Mass production of glass strands was discovered in 1932, when Games Slayter, a researcher at [[Company:Owens-Illinois|Owens-Illinois]] accidentally directed a jet of compressed air at a stream of molten glass and produced fibres. A patent for this method of producing glass wool was first applied for in 1933.<ref>[http://www.google.com/patents?id=0EMBAAAAEBAJ&dq=%22G.+Slayter%22 US Patent Number 2133235: Method & Apparatus for Making Glass Wool] First Slayter glass wool patent, 1933.</ref>
Owens joined with the Corning company in 1935 and the method was adapted by Owens Corning to produce its patented "fibreglas" (one "s") in 1936. Originally, fibreglas was a [[Engineering:Glass wool|glass wool]] with fibres entrapping a great deal of gas, making it useful as an insulator, especially at high temperatures.

A suitable resin for combining the "fibreglas" with a plastic to produce a composite material, was developed in 1936 by [[Company:DuPont (1802–2017)|du Pont]]. The first ancestor of modern polyester resins is Cyanamid's resin of 1942. [[Chemistry:Peroxide|Peroxide]] curing systems were used by then.<ref>50 years of reinforced plastic boats, George Marsh, 8 October 2006, http://www.reinforcedplastics.com/view/1461/50-years-of-reinforced-plastic-boats-/ {{Webarchive|url=https://web.archive.org/web/20100806142114/http://www.reinforcedplastics.com/view/1461/50-years-of-reinforced-plastic-boats- |date=6 August 2010 }}</ref> With the combination of fibreglas and resin the gas content of the material was replaced by plastic. This reduced the insulation properties to values typical of the plastic, but now for the first time the composite showed great strength and promise as a structural and building material. Confusingly, many glass fibre composites continued to be called "fibreglass" (as a generic name) and the name was also used for the low-density glass wool product containing gas instead of plastic.

<!-- WP:NFCC violation: [[File:Soybean Car 1941.jpg|thumb|right|Ford prototype plastic car]] -->
[[File:EL-2000-00186.jpg|thumb|right|Fairchild F-46]]
Ray Greene of [[Company:Owens Corning|Owens Corning]] is credited with producing the first composite boat in 1937, but did not proceed further at the time due to the brittle nature of the plastic used. In 1939, Russia was reported to have constructed a passenger boat of plastic materials, and the United States a fuselage and wings of an aircraft.<ref>Notable Progress – the use of plastics, ''Evening Post'', Wellington, New Zealand, Volume CXXVIII, Issue 31, 5 August 1939, Page 28</ref> The first car to have a fibre-glass body was the 1946 [[Company:Stout Scarab|Stout Scarab]]. Only one of this model was built.<ref>Car of the future in plastics, ''The Mercury'' (Hobart, Tasmania), Monday 27 May 1946, page 16</ref> The Ford prototype of 1941 could have been the first plastic car, but there is some uncertainty around the materials used as it was destroyed shortly afterwards.<ref>{{cite news|title=Post war automobile|url=https://www.newspapers.com/image/77040054|newspaper=Bradford Daily Record|date=28 March 1941|page=12|via = Newspapers.com|access-date = 17 June 2015}} {{Open access}}</ref><ref>{{cite news|title=Post war automobile|url=https://www.newspapers.com/image/22323497|newspaper=The Corpus Christi Times|date=12 January 1942|page=3|via = Newspapers.com|access-date = 17 June 2015}} {{Open access}}</ref>
 
The first fibre-reinforced plastic plane was either the [[Engineering:Fairchild F-46|Fairchild F-46]], first flown on 12 May 1937, or the Californian built Bennett Plastic Plane.<ref>{{cite news|title=Plastic planes from molds is plan of army |url=https://www.newspapers.com/image/24978378/?terms=%22plastic%2Bplane%22|newspaper=Greeley Daily Tribune|date=24 June 1938|page=2|via = Newspapers.com|access-date = 12 August 2015 }} {{Open access}}</ref> A fibreglass fuselage was used on a modified [[Engineering:Vultee BT-13 Valiant|Vultee BT-13A]] designated the XBT-16 based at Wright Field in late 1942.<ref>American Warplanes of World War II, David Donald, Aerospace Publishing Limited, 1995, pages 251–252, {{ISBN|1-874023-72-7}}</ref> In 1943, further experiments were undertaken building structural aircraft parts from composite materials resulting in the first plane, a Vultee BT-15, with a GFRP fuselage, designated the XBT-19, being flown in 1944.<ref>Accelerating utilization of new materials, National Research Council (U.S.) Committee on Accelerated Utilization of New Materials, Washington, National Academy of Sciences – National Academy of Engineering, Springfield, Va, 1971, pages 56–57 by W P Conrardy</ref><ref>Moulded glass fibre Sandwich Fuselages for BT-15 Airplane, Army Air Force Technical Report 5159, 8 November 1944</ref><ref>Reinforced plastics handbook; Donald V. Rosato, Dominick V. Rosato, and John Murphy; Elsevier; 2004; page 586</ref>  A significant development in the tooling for GFRP components had been made by Republic Aviation Corporation in 1943.<ref>{{cite web |title = Composites Overview|first1= Tim|first2= Palucka |last1= Bernadette|last2= Bensaude-Vincent|url = http://authors.library.caltech.edu/5456/1/hrst.mit.edu/hrs/materials/public/composites/Composites_Overview.htm|website = History of Recent Science & Technology|date = 19 October 2002}}</ref>

Carbon fibre production began in the late 1950s and was used, though not widely in British industry until the early 1960s. Aramid fibres were being produced around this time also, appearing first under the trade name [[Engineering:Nomex|Nomex]] by [[Company:DuPont|DuPont]]. Today, each of these fibres is used widely in industry for any applications that require plastics with specific strength or elastic qualities. Glass fibres are the most common across all industries, although carbon-fibre and carbon-fibre-aramid composites are widely found in aerospace, automotive and sporting good applications.<ref name="Gunter"/> These three ([[Chemistry:Glass|glass]], carbon, and [[Chemistry:Aramid|aramid]]) continue to be the important categories of fibre used in FRP.

Global polymer production on the scale present today began in the mid 20th century, when low material and productions costs, new production technologies and new product categories, combined to make polymer production economical. The industry finally matured in the late 1970s, when world polymer production surpassed that of steel, making polymers the ubiquitous material that they are today. Fibre-reinforced plastics have been a significant aspect of this industry from the beginning.

==Process definition==
A [[Chemistry:Polymer|polymer]] is generally manufactured by [[Chemistry:Step-growth polymerization|step-growth polymerization]] or addition polymerization. When one or more polymers are combined with various agents to enhance or in any way alter their material properties, the result is referred to as a [[Chemistry:Plastic|plastic]]. [[Chemistry:Composite material|Composite plastics]] refers to those types of plastics that result from bonding two or more homogeneous materials with different material properties to derive a final product with certain desired material and mechanical properties. Fibre-reinforced plastics are a category of composite plastics that specifically use fibre materials to mechanically enhance the strength and [[Physics:Elastic modulus|elasticity]] of plastics.

The original plastic material without fibre reinforcement is known as the [[Chemistry:Composite material#Matrices|matrix]] or [[Chemistry:Binder (material)|binding agent]]. The matrix is a tough but relatively weak plastic that is reinforced by stronger stiffer reinforcing filaments or fibres. The extent that strength and elasticity are enhanced in a fibre-reinforced plastic depends on the mechanical properties of both the fibre and matrix, their volume relative to one another, and the fibre length and orientation within the matrix.<ref name="Smallman">Smallman, R. E., and R.J. Bishop. [https://books.google.com/books?id=S7zWcHBnMzAC&q=Modern+Physical+Metallurgy+and+Materials+Engineering ''Modern Physical Metallurgy and Materials Engineering'']. 6th ed. Oxford: Butterworth-Heinemann, 1999.</ref>  Reinforcement of the matrix occurs by definition when the FRP material exhibits increased strength or elasticity relative to the strength and elasticity of the matrix alone.<ref name="Gunter">Erhard, Gunter. [https://books.google.com/books?id=mesU4WbE5CIC&q=Designing+with+Plastics ''Designing with Plastics'']. Trans. Martin Thompson. Munich: Hanser Publishers, 2006.</ref>

==Process description==
FRP involves two distinct processes, the first is the process whereby the fibrous material is manufactured and formed, the second is the process whereby fibrous materials are bonded with the matrix during moulding.<ref name="Gunter"/>

===Fibre===

====Manufacture of fibre fabric====
Reinforcing Fibre is manufactured in both two-dimensional and three-dimensional orientations:
#Two-dimensional fibre glass-reinforced polymer is characterized by a laminated structure in which the fibres are only aligned along the plane in [[Cartesian coordinate system|x-direction, and y-direction]] of the material. This means that no fibres are aligned in the through-thickness or the [[Cartesian coordinate system|z-direction]], this lack of alignment in the through thickness can create a disadvantage in cost and processing. Costs and labour increase because conventional processing techniques used to fabricate composites, such as wet hand lay-up, autoclave and resin transfer moulding, require a high amount of skilled labour to cut, stack and consolidate into a preformed component.
#Three-dimensional fibreglass-reinforced polymer composites are materials with three-dimensional fibre structures that incorporate fibres in the [[Cartesian coordinate system|x-direction, y-direction and z-direction]]. The development of three-dimensional orientations arose from industry's need to reduce fabrication costs, to increase through-thickness mechanical properties, and to improve impact damage tolerance; all were problems associated with two-dimensional fibre-reinforced polymers.

==== Manufacture of fibre preforms ====
Fibre preforms are how the fibres are manufactured before being bonded to the matrix. Fibre preforms are often manufactured in sheets, continuous mats, or as continuous filaments for spray applications. The four major ways to manufacture the fibre preform is through the textile processing techniques of weaving, [[Chemistry:Knitting|knitting]], braiding and stitching.

#Weaving can be done in a conventional manner to produce two-dimensional fibres as well as in a multilayer weaving that can create three-dimensional fibres. However, multilayer weaving requires multiple layers of warp yarns to create fibres in the z-direction, creating a few disadvantages in manufacturing, namely the time to set up all the warp yarns on the [[Engineering:Loom|loom]]. Therefore, most multilayer weaving is currently used to produce relatively narrow width products, or high value products where the cost of the preform production is acceptable. Another one of the main problems facing the use of multilayer woven fabrics is the difficulty in producing a fabric that contains fibres oriented at other than right angles to each other.
#The second major way of manufacturing fibre preforms is Braiding. Braiding is suited to the manufacture of narrow width flat or tubular fabric and is not as capable as weaving in the production of large volumes of wide fabrics. Braiding is done over top of mandrels that vary in cross-sectional shape or dimension along their length. Braiding is limited to objects about a brick in size. Unlike standard weaving, braiding can produce fabric that contains fibres at 45-degree angles to one another. Braiding three-dimensional fibres can be done using four-step, two-step or Multilayer Interlock Braiding. Four-step or row and column braiding utilizes a flat bed containing rows and columns of yarn carriers that form the shape of the desired preform. Additional carriers are added to the outside of the array, the precise location and quantity of which depends upon the exact preform shape and structure required. There are four separate sequences of row and column motion, which act to interlock the yarns and produce the braided preform. The yarns are mechanically forced into the structure between each step to consolidate the structure, as a reed is used in weaving. Two-step braiding is unlike the four-step process because the two-step process includes a large number of yarns fixed in the axial direction and a lesser number of braiding yarns. The process consists of two steps in which the braiding carriers move completely through the structure between the axial carriers. This relatively simple sequence of motions is capable of forming preforms of essentially any shape, including circular and hollow shapes. Unlike the four-step process, the two-step process does not require mechanical compaction: the motions involved in the process allows the braid to be pulled tight by yarn tension alone. The last type of braiding is multi-layer interlocking braiding that consists of a number of standard circular braiders being joined together to form a cylindrical braiding frame. This frame has a number of parallel braiding tracks around the circumference of the cylinder but the mechanism allows the transfer of yarn carriers between adjacent tracks forming a multilayer braided fabric with yarns interlocking to adjacent layers. The multilayer interlock braid differs from both the four-step and two-step braids in that the interlocking yarns are primarily in the plane of the structure and thus do not significantly reduce the in-plane properties of the preform. The four-step and two-step processes produce a greater degree of interlinking as the braiding yarns travel through the thickness of the preform, but therefore contribute less to the in-plane performance of the preform. A disadvantage of the multilayer interlock equipment is that due to the conventional sinusoidal movement of the yarn carriers to form the preform, the equipment is not able to have the density of yarn carriers that is possible with the two-step and four-step machines.
#Knitting fibre preforms can be done with the traditional methods of Warp and [Weft] Knitting, and the fabric produced is often regarded by many as two-dimensional fabric, but machines with two or more needle beds are capable of producing multilayer fabrics with yarns that traverse between the layers. Developments in electronic controls for needle selection and knit loop transfer, and in the sophisticated mechanisms that allow specific areas of the fabric to be held and their movement controlled, have allowed the fabric to be formed into the required three-dimensional preform shape with a minimum of material wastage.
#Stitching is arguably the simplest of the four main textile manufacturing techniques and one that can be performed with the smallest investment in specialized machinery. Basically stitching consists of inserting a needle, carrying the stitch thread, through a stack of fabric layers to form a 3D structure. The advantages of stitching are that it is possible to stitch both dry and prepreg fabric, although the tackiness of the prepreg makes the process difficult and generally creates more damage within the prepreg material than in the dry fabric. Stitching also utilizes the standard two-dimensional fabrics that are commonly in use within the composite industry, so there is a sense of familiarity with the material systems. The use of standard fabric also allows a greater degree of flexibility in the fabric lay-up of the component than is possible with the other textile processes, which have restrictions on the fibre orientations that can be produced.<ref>Tong, L, A.P. Mouritz, and M.k. Bannister. [https://books.google.com/books?id=QWfsk0_vFWAC&q=3D+Fibre+Reinforced+Polymer+Composites 3D Fibre-Reinforced Polymer Composites]. Oxford: Elsevier, 2002.</ref>

===Forming processes===
A rigid structure is usually used to establish the shape of FRP components. Parts can be laid up on a flat surface referred to as a "caul plate" or on a cylindrical structure referred to as a "mandrel". However, most fibre-reinforced plastic parts are created with a mould or "tool". Moulds can be concave female moulds, male moulds, or the mould can completely enclose the part with a top and bottom mould.

The moulding processes of FRP plastics begins by placing the fibre preform on or in the mould. The fibre preform can be dry fibre, or fibre that already contains a measured amount of resin called "prepreg". Dry fibres are "wetted" with resin either by hand or the resin is injected into a closed mould. The part is then cured, leaving the  matrix and fibres in the shape created by the mould. Heat and/or pressure are sometimes used to cure the resin and improve the quality of the final part.
The different methods of forming are listed below.

====Bladder moulding====
Individual sheets of prepreg material are laid up and placed in a female-style mould along with a balloon-like bladder. The mould is closed and placed in a heated press. Finally, the bladder is pressurized forcing the layers of material against the mould walls.

====Compression moulding====
When the raw material (plastic block, rubber block, plastic sheet, or granules) contains reinforcing fibres, a compression moulded part qualifies as a fibre-reinforced plastic. More typically the plastic preform used in compression moulding does not contain reinforcing fibres. In compression moulding, a "preform" or "charge", of [[Chemistry:Sheet moulding compound|SMC]], BMC is placed into mould cavity. The mould is closed and the material is formed & cured inside by pressure and heat. Compression moulding offers excellent detailing for geometric shapes ranging from pattern and relief detailing to complex curves and creative forms, to [[Engineering:Precision engineering|precision engineering]] all within a maximum curing time of 20 minutes.<ref name="quatro">{{cite web|url=http://www.quatrocomposites.com/comp101proc.htm|archive-url=https://web.archive.org/web/20080215010801/http://www.quatrocomposites.com/comp101proc.htm|url-status=dead|archive-date=15 February 2008|title=Quatro Composites Processes 101: Molding Carbon Composite Parts|date=15 February 2008|access-date=2 April 2018}}</ref>

====Autoclave and vacuum bag====
Individual sheets of prepreg material are laid-up and placed in an open mould. The material is covered with release film, bleeder/breather material and a [[Chemistry:Composite material#Vacuum bag moulding|vacuum bag]]. A vacuum is pulled on part and the entire mould is placed into an autoclave (heated pressure vessel). The part is cured with a continuous vacuum to extract entrapped gasses from laminate. This is a very common process in the aerospace industry because it affords precise control over moulding due to a long, slow cure cycle that is anywhere from one to several hours.<ref>{{cite journal|last=Dogan|first=Fatih|author2=Hadavinia, Homayoun |author3=Donchev, Todor |author4= Bhonge, Prasannakumar S. |title=Delamination of impacted composite structures by cohesive zone interface elements and tiebreak contact|journal=Central European Journal of Engineering|date=5 August 2012|volume=2|issue=4|pages=612–626|doi=10.2478/s13531-012-0018-0|bibcode=2012CEJE....2..612D|hdl=10057/16013|url=http://eprints.kingston.ac.uk/23711/|doi-access=free|hdl-access=free}}</ref> This precise control creates the exact laminate geometric forms needed to ensure strength and safety in the aerospace industry, but it is also slow and labour-intensive, meaning costs often confine it to the aerospace industry.<ref name="quatro"/>

====Mandrel wrapping====
Sheets of prepreg material are wrapped around a steel or aluminium mandrel. The prepreg material is compacted by nylon or polypropylene cello tape. Parts are typically batch cured by vacuum bagging and hanging in an oven. After cure, the cello and mandrel are removed leaving a hollow carbon tube. This process creates strong and robust hollow carbon tubes.

====Wet layup====
Wet layup forming combines fibre reinforcement and the matrix as they are placed on the forming tool.<ref name="Gunter"/> Reinforcing fibre layers are placed in an open mould and then saturated with a wet resin by pouring it over the fabric and working it into the fabric. The mould is then left so that the resin will cure, usually at room temperature, though heat is sometimes used to ensure a proper cure. Sometimes a vacuum bag is used to compress a wet layup. Glass fibres are most commonly used for this process, the results are widely known as fibreglass, and is used to make common products like skis, canoes, kayaks and surf boards.<ref name="quatro"/>

====Chopper gun====
Continuous strands of fibreglass are pushed through a hand-held gun that both chops the strands and combines them with a catalysed resin such as polyester. The impregnated chopped glass is shot onto the mould surface in whatever thickness and design the human operator thinks is appropriate. This process is good for large production runs at economical cost, but produces geometric shapes with less strength than other moulding processes and has poor dimensional tolerance.<ref name="quatro"/>

====Filament winding====
Machines pull fibre bundles through a wet bath of resin and wound over a rotating steel mandrel in specific orientations. Parts are cured either room temperature or elevated temperatures. Mandrel is extracted, leaving a final geometric shape but can be left in some cases.<ref name="quatro"/>

====Pultrusion====
Fibre bundles and slit fabrics are pulled through a wet bath of resin and formed into the rough part shape. Saturated material is extruded from a heated closed die curing while being continuously pulled through die. Some of the end products of pultrusion are structural shapes, i.e. I beam, angle, channel and flat sheet. These materials can be used to create all sorts of fibreglass structures such as ladders, platforms, handrail systems tank, pipe and pump supports.<ref name="quatro"/>

====Resin transfer moulding====
Also called '''resin infusion'''. Fabrics are placed into a mould into which wet resin is then injected. Resin is typically pressurized and forced into a cavity which is under vacuum in [[Biology:Out of autoclave composite manufacturing|resin transfer moulding]]. Resin is entirely pulled into cavity under vacuum in vacuum-assisted resin transfer moulding. This moulding process allows precise tolerances and detailed shaping, but can sometimes fail to fully saturate the fabric leading to weak spots in the final shape.<ref name="quatro"/>

==Advantages and limitations==
FRP allows the alignment of the glass fibres of thermoplastics to suit specific design programs. Specifying the orientation of reinforcing fibres can increase the strength and resistance to deformation of the polymer. Glass reinforced polymers are strongest and most resistive to deforming forces when the polymers fibres are parallel to the force being exerted, and are weakest when the fibres are perpendicular. Thus, this ability is at once both an advantage or a limitation depending on the context of use. Weak spots of perpendicular fibres can be used for natural hinges and connections, but can also lead to material failure when production processes fail to properly orient the fibres parallel to expected forces. When forces are exerted perpendicular to the orientation of fibres, the strength and elasticity of the polymer is less than the matrix alone. In cast resin components made of glass reinforced polymers such as UP and EP, the orientation of fibres can be oriented in two-dimensional and three-dimensional weaves. This means that when forces are possibly perpendicular to one orientation, they are parallel to another orientation; this eliminates the potential for weak spots in the polymer.

===Failure modes===
Structural failure can occur in FRP materials when:
*Tensile forces stretch the matrix more than the fibres, causing the material to shear at the interface between matrix and fibres.
*Tensile forces near the end of the fibres exceed the tolerances of the matrix, separating the fibres from the matrix.
*Tensile forces can also exceed the tolerances of the fibres causing the fibres themselves to fracture leading to material failure.<ref name="Gunter"/>

==Material requirements==
A [[Chemistry:Thermoset polymer matrix|thermoset polymer matrix]] material, or engineering grade thermoplastic polymer matrix material, must meet certain requirements in order to first be suitable for FRPs and ensure a successful reinforcement of itself. The matrix must be able to properly saturate, and preferably bond chemically with the fibre reinforcement for maximum adhesion within a suitable curing period. The matrix must also completely envelop the fibres to protect them from cuts and notches that would reduce their strength, and to transfer forces to the fibres. The fibres must also be kept separate from each other so that if failure occurs it is localized as much as possible, and if failure occurs the matrix must also debond from the fibre for similar reasons. Finally, the matrix should be of a plastic that remains chemically and physically stable during and after the reinforcement and moulding processes. To be suitable as reinforcement material, fibre additives must increase the tensile strength and modulus of elasticity of the matrix and meet the following conditions; fibres must exceed critical fibre content; the strength and rigidity of fibres itself must exceed the strength and rigidity of the matrix alone; and there must be optimum bonding between fibres and matrix

===Glass fibre===
"Fibreglass reinforced plastics" or FRPs (commonly referred to simply as fibreglass) use textile grade glass fibres. These textile fibres are different from other forms of glass fibres used to deliberately trap air, for insulating applications (see [[Engineering:Glass wool|glass wool]]). Textile glass fibres begin as varying combinations of SiO<sub>2</sub>, Al<sub>2</sub>O<sub>3</sub>, B<sub>2</sub>O<sub>3</sub>, CaO, or MgO in powder form. These mixtures are then heated through direct melting to temperatures around 1300 degrees Celsius, after which dies are used to extrude filaments of glass fibre in diameter ranging from 9 to 17&nbsp;µm. These filaments are then wound into larger threads and spun onto bobbins for transportation and further processing. Glass fibre is by far the most popular means to reinforce plastic and thus enjoys a wealth of production processes, some of which are applicable to aramid and carbon fibres as well owing to their shared fibrous qualities.

Roving is a process where filaments are spun into larger diameter threads. These threads are then commonly used for woven reinforcing glass fabrics and mats, and in spray applications.

Fibre fabrics ( [[Chemistry:Glass cloth|glass cloth]], etc) are web-form fabric reinforcing material that has both warp and weft directions. Fibre mats are web-form non-woven mats of glass fibres. Mats are manufactured in cut dimensions with chopped fibres, or in continuous mats using continuous fibres. Chopped fibre glass is used in processes where lengths of glass threads are cut between 3 and 26&nbsp;mm, threads are then used in plastics most commonly intended for moulding processes. Glass fibre short strands are short 0.2–0.3&nbsp;mm strands of glass fibres that are used to reinforce thermoplastics most commonly for injection moulding.

===Carbon fibre===

Carbon fibres are created when polyacrylonitrile fibres (PAN), Pitch resins, or Rayon are carbonized (through oxidation and thermal pyrolysis) at high temperatures. Through further processes of graphitizing or stretching, the fibres strength or elasticity can be enhanced respectively. Carbon fibres are manufactured in diameters analogous to glass fibres with diameters ranging from 4 to 17&nbsp;µm. These fibres wound into larger threads for transportation and further production processes.<ref name="Gunter"/>  Further production processes include weaving or braiding into carbon fabrics, cloths and mats analogous to those described for glass that can then be used in actual reinforcements.<ref name="Smallman"/>

===Aramid fibre===
Aramid fibres are most commonly known as Kevlar, Nomex and Technora. Aramids are generally prepared by the reaction between an amine group and a carboxylic acid halide group (aramid);.<ref name="Smallman"/> Commonly, this occurs when an aromatic polyamide is spun from a liquid concentration of sulphuric acid into a crystallized fibre.<ref name="Gunter"/> Fibres are then spun into larger threads in order to weave into large ropes or woven fabrics (aramid).<ref name="Smallman"/> Aramid fibres are manufactured with varying grades based on strength and rigidity, so that the material can be adapted to meet specific design requirements, such as cutting the tough material during manufacture.<ref name="Gunter"/>

==Example polymer and reinforcement combinations==
{| class="wikitable"
|-
! Reinforcing material<ref name="Gunter"/>
! Most common matrix materials
! Properties improved
|-
| Glass fibres
| UP, [[Chemistry:Epoxide|EP]], [[Chemistry:Polyamide|PA]], [[Physics:Polycarbonate|PC]], [[Chemistry:Polyoxymethylene|POM]], PP, [[Chemistry:Polybutylene terephthalate|PBT]], [[Chemistry:Vinyl ester resin|VE]]
| Strength, elasticity, heat resistance
|-
| Wood fibres
| PE, PP, [[Chemistry:Acrylonitrile butadiene styrene|ABS]], HDPE, [[Chemistry:Polylactic acid|PLA]]
| Flexural strength, tensile modulus, tensile strength 
|-
| Carbon and aramid fibres
| EP, UP, VE, PA
| Elasticity, tensile strength, compression strength, electrical strength.
|-
| Inorganic particulates
| Semicrystalline thermoplastics, UP
| Isotropic shrinkage, abrasion, compression strength
|-
| Microspheres
| Glass microspheres
| Weight reduction relative to solid fillers
|}

==Applications==
[[File:Glass-aramid-hybrid-area used-for-reinforced-plastics.jpg|thumb|Glass-aramid-hybrid fabric (for high tension and compression)]]
Fibre-reinforced plastics are best suited for any design program that demands weight savings, precision engineering, definite tolerances, and the simplification of parts in both production and operation.The fibers provide strength and stiffness to the material, while the polymer matrix holds the fibers together and transfers loads between them. FRP composites have a wide range of applications across various industries due to their unique combination of properties, including high strength-to-weight ratio, corrosion resistance, and design flexibility. A moulded polymer product is cheaper, faster, and easier to manufacture than a cast aluminium or steel product, and maintains similar and sometimes better tolerances and material strengths.

===Carbon-fibre-reinforced polymers===
Rudder of Airbus A310 
*Advantages over a traditional rudder made from sheet aluminium are:
**25% reduction in weight
**95% reduction in components by combining parts and forms into simpler moulded parts.
**Overall reduction in production and operational costs, economy of parts results in lower production costs and the weight savings create fuel savings that lower the operational costs of flying the aeroplane.

===Glass-fibre-reinforced polymers===
Engine intake manifolds are made from glass-fibre-reinforced PA 66.
*Advantages this has over cast aluminium manifolds are:
**Up to a 60% reduction in weight
**Improved surface quality and aerodynamics
**Reduction in components by combining parts and forms into simpler moulded shapes.

Automotive gas and clutch pedals made from glass-fibre-reinforced PA 66 (DWP 12–13)
*Advantages over stamped aluminium are:
**Pedals can be moulded as single units combining both pedals and mechanical linkages simplifying the production and operation of the design.
**Fibres can be oriented to reinforce against specific stresses, increasing the durability and safety.

Aluminium windows, doors and façades are thermally insulated by using thermal insulation plastics made of glass fibre reinforced polyamide. In 1977 Ensinger GmbH produced first insulation profile for window systems.

=== Structural applications ===
FRP can be applied to strengthen the [[Physics:Beam (structure)|beams]], [[Earth:Column|column]]s,<ref>{{Cite journal |last1=Naderpour |first1=H. |last2=Nagai |first2=K. |last3=Fakharian |first3=P. |last4=Haji |first4=M. |date=2019-05-01 |title=Innovative models for prediction of compressive strength of FRP-confined circular reinforced concrete columns using soft computing methods |url=https://www.sciencedirect.com/science/article/pii/S0263822318342740 |journal=Composite Structures |language=en |volume=215 |pages=69–84 |doi=10.1016/j.compstruct.2019.02.048 |s2cid=139800570 |issn=0263-8223}}</ref> and slabs of buildings and bridges. It is possible to increase the strength of structural members even after they have been severely damaged due to loading conditions. In the case of damaged [[Physics:Reinforced concrete|reinforced concrete]] members, this would first require the repair of the member by removing loose debris and filling in cavities and cracks with mortar or [[Chemistry:Epoxy|epoxy resin]]. Once the member is repaired, strengthening can be achieved through wet, hand lay-up of fibre sheets impregnated with epoxy resin, applied to the cleaned and prepared surfaces of the member.

Two techniques are typically adopted for the strengthening of beams, depending on the strength enhancement desired: [[Physics:Flexural strength|flexural strength]]ening or [[Engineering:Shear strength|shear strength]]ening. In many cases it may be necessary to provide both strength enhancements. For the flexural strengthening of a beam, FRP sheets or plates are applied to the tension face of the member (the bottom face for a simply supported member with applied top loading or gravity loading). Principal tensile fibres are oriented parallel to the beam's longitudinal axis, similar to its internal flexural steel reinforcement. This increases the beam strength and its [[Physics:Stiffness|stiffness]] ([[Structural load|load]] required to cause unit deflection), but decreases the [[Engineering:Deflection (engineering)|deflection capacity]] and ductility.

For the shear strengthening of a beam, the FRP is applied on the web (sides) of a member with fibres oriented transverse to the beam's longitudinal axis. Resisting of shear forces is achieved in a similar manner as internal steel stirrups, by bridging shear cracks that form under applied loading. FRP can be applied in several configurations, depending on the exposed faces of the member and the degree of strengthening desired, this includes: side bonding, U-wraps (U-jackets), and closed wraps (complete wraps). Side bonding involves applying FRP to the sides of the beam only. It provides the least amount of shear strengthening due to failures caused by [[Chemistry:Adhesive#Failure of the adhesive joint|de-bonding]] from the concrete surface at the FRP free edges. For U-wraps, the FRP is applied continuously in a 'U' shape around the sides and bottom (tension) face of the beam. If all faces of a beam are accessible, the use of closed wraps is desirable as they provide the most strength enhancement. Closed wrapping involves applying FRP around the entire perimeter of the member, such that there are no free ends and the typical failure mode is [[Physics:Fracture|rupture]] of the fibres. For all wrap configurations, the FRP can be applied along the length of the member as a continuous sheet or as discrete strips, having a predefined minimum width and spacing.

Slabs may be strengthened by applying FRP strips at their bottom (tension) face. This will result in better flexural performance, since the tensile resistance of the slabs is supplemented by the tensile strength of FRP. In the case of beams and slabs, the effectiveness of FRP strengthening depends on the performance of the resin chosen for bonding. This is particularly an issue for shear strengthening using side bonding or U-wraps. Columns are typically wrapped with FRP around their perimeter, as with closed or complete wrapping. This not only results in higher shear resistance, but more crucial for [[Engineering:Reinforced concrete column|column design]], it results in increased compressive strength under axial loading. The FRP wrap works by restraining the lateral expansion of the column, which can enhance confinement in a similar manner as spiral reinforcement does for the column core.<ref>{{cite journal |last1=Megalooikonomou |first1=Konstantinos G. |last2=Monti |first2=Giorgio |last3=Santini |first3=Silvia |title=Constitutive Model for Fiber –Reinforced Polymer - and Tie – Confined Concrete |journal=ACI Structural Journal |year=2012 |volume=109 |issue=4 |pages=569–578 |doi= 10.14359/51683876}}</ref><ref>{{cite journal |last1=Megalooikonomou |first1=Konstantinos G. |last2=Papavasileiou |first2=Georgios S.|title=Analytical stress-strain model for FRP-confined rectangular RC columns |journal=  Frontiers in Built Environment|year=2019 |volume=5 |pages=39 |doi= 10.3389/fbuil.2019.00039|doi-access=free }}</ref>

=== Elevator cable ===
In June 2013, KONE elevator company announced Ultrarope for use as a replacement for steel cables in elevators. It seals the carbon fibres in high-friction [[Chemistry:Polymer|polymer]]. Unlike steel cable, Ultrarope was designed for buildings that require up to {{convert|1000|m|abbr=on}} of lift. Steel elevators top out at {{convert|500|m|abbr=on}}. The company estimated that in a {{convert|500|m|abbr=on}} high building, an elevator would use 15% less electrical power than a steel-cabled version. As of June 2013, the product had passed all European Union and United States certification tests.<ref name="phys">{{cite web|url=http://phys.org/news/2013-06-ultrarope-one-stop-tall.html |title=UltraRope announced to one-stop zoom up tall buildings |publisher=Phys.org |access-date=13 June 2013}}</ref>

==Design considerations==
FRP is used in designs that require a measure of strength or modulus of elasticity for which non-reinforced plastics and other material choices are ill-suited, either mechanically or economically. The primary design consideration for using FRP is to ensure that the material is used economically and in a manner that takes advantage of its specific structural characteristics, but this is not always the case. The orientation of fibres  creates a material weakness perpendicular to the fibres. Thus the use of fibre reinforcement and their orientation affects the strength, rigidity, elasticity and hence the functionality of the final product itself. Orienting the fibres either unidirectionally, 2-dimensionally, or 3-dimensionally during production affects the strength, flexibility, and elasticity of the final product. Fibres oriented in the direction of applied forces display greater resistance to distortion from these forces, thus areas of a product that must withstand forces will be reinforced with fibres oriented parallel to the forces, and areas that require flexibility, such as natural hinges, will have fibres oriented perpendicular to the forces.

Orienting the fibres in more dimensions avoids this either-or scenario and creates objects that seek to avoid any specific weakness due to the unidirectional orientation of fibres. The properties of strength, flexibility and elasticity can also be magnified or diminished through the geometric shape and design of the final product. For example, ensuring proper wall thickness and creating multifunctional geometric shapes that can be moulded as a single piece enhances the material and structural integrity of the product by reducing the requirements for joints, connections, and hardware.<ref name="Gunter"/>

===Disposal and recycling concerns===
As a subset of plastic, FR plastics are liable to a number of the issues and concerns in plastic waste disposal and recycling. Plastics pose a particular challenge in recycling because they are derived from polymers and monomers that often cannot be separated and returned to their virgin states. For this reason not all plastics can be recycled for re-use, in fact some estimates claim only 20% to 30% of plastics can be recycled at all. Fibre-reinforced plastics and their matrices share these disposal and environmental concerns. Investigation of safe disposal methods has led to two main variations involving the application of intense heat: in one binding agents are burned off - in the process recapturing some of the sunk material cost in the form of heat - and incombustible elements captured by filtration; in the other the incombustible material is burned in a cement kiln, the fibres becoming an integral part of the resulting cast material.<ref>https://compositesuk.co.uk/system/files/documents/Composite%20Recycling.pdf {{Bare URL PDF|date=March 2022}}</ref> In addition to concerns regarding safe disposal, the fact that the fibres themselves are difficult to remove from the matrix and preserve for re-use means FRP's amplify these challenges. FRP's are inherently difficult to separate into base materials, that is into fibre and matrix, and the matrix is difficult to separate into usable plastics, polymers, and monomers. These are all concerns for environmentally-informed design today. Plastics do often offer savings in energy and economic savings in comparison to other materials. In addition, with the advent of new more environmentally friendly matrices such as [[Chemistry:Bioplastic|bioplastic]]s and [[Physics:Ultraviolet|UV]]-degradable plastics, FRP will gain environmental sensitivity.<ref name="Smallman"/>

==See also==
* Long-fibre-reinforced thermoplastic
* [[Chemistry:Pre-preg|Pre-preg]]
* [[Chemistry:Composite material|Composite material]]

== References ==
{{reflist|30em}}


[[Category:Composite materials]]
[[Category:Plastics]]
[[Category:Structural engineering]]
[[Category:Fibre-reinforced polymers]]
[[Category:Materials science]]

{{Sourceattribution|Fibre-reinforced plastic}}